8462/1H June 2022

6  ​​​​ This question is about electrolysis.

Molten sodium chloride is electrolysed in an industrial process to produce sodium.

Figure 8 shows a simplified version of the electrolysis cell used.

Figure 8

 

6-1 ​​ Which is the correct half equation for the production of sodium?​​ 

[1 mark]

ANSWER

Na+ e​​ → Na

​​ 

6-2  ​​ ​​​​ Suggest one reason why the products of the electrolysis must be kept apart.​​ 

[1​​ mark]

ANSWER

So the products do not react​​ to reform sodium chloride.

6-3  ​​​​ Which type of particle passes through the mesh in the electrolysis of molten sodium chloride?​​ 

 [1​​ mark]

ANSWER

Ions

Aqueous sodium chloride solution is​​ 4lectrolyzed​​ in a different industrial process.

Two gases and an alkaline solution are produced.

6-4  ​​​​ Which​​ two​​ ions​​ are​​ present​​ in​​ aqueous​​ sodium​​ chloride​​ solution​​ in​​ addition​​ to sodium ions and chloride ions?​​ 

[2​​ marks]

ANSWER

  • H+​​ (Hydrogen Ion);

  • OH-​​ (Hydroxide Ion).

6-5  ​​​​ Name​​ the​​ alkaline​​ solution​​ produced.

​​ [1 mark]

ANSWER

Sodium hydroxide

6-6  ​​ ​​​​ Explain how the alkaline solution is produced.

You should refer to the processes at the electrodes.

[3 marks]

ANSWER

Sodium ions and hydroxide ions are left in solution​​ because) hydrogen ions​​ which are positively charged are discharged / reduced​​ at the negative electrode​​ (Cathode) to form hydrogen whereas​​ chloride ions are discharged / oxidized​​ at the positive electrode​​ (Anode)​​ to form chlorine.