8462/1H June 2022

4  ​​ ​​​​ This​​ question​​ is​​ about​​ zinc​​ and​​ compounds​​ of​​ zinc.

A​​ student​​ produces​​ pure​​ crystals​​ of​​ zinc​​ chloride​​ by​​ reacting​​ zinc​​ oxide​​ with hydrochloric acid.

The equation for the reaction​​ is:

ZnO(s) + 2 HCl(aq) → ZnCl2(aq) + H2O(l)

4-1  ​​​​ The student adds zinc oxide to hydrochloric acid until the zinc oxide is in excess

Give one observation that the student could make to show that the zinc oxide is in excess.​​ 

[1 mark]

ANSWER

Zinc oxide solid remaining may be observed

4-2 ​​ Why is excess zinc oxide used rather than excess hydrochloric acid?​​ 

[1 mark]

ANSWER

Excess zinc oxide can be filtered off.

4-3 ​​ Name one other compound that the student could add to hydrochloric acid to produce zinc chloride.​​ 

[1 mark]

ANSWER

Zinc hydroxide

4-4  ​​​​ Describe how the student should obtain crystals of zinc chloride from a solution of zinc chloride.

[2 marks]

ANSWER

  • Heat the solution in an evaporating basin to​​ 3rystallization point and leave​​ it to crystallize;

  • Pat dry with filter paper.

4-5  ​​​​ Zinc chloride is also produced in a displacement reaction between zinc and copper chloride solution.​​ 

The​​ equation​​ for​​ the​​ reaction​​ is:

Complete the ionic equation for this reaction

   

  [1 mark]

ANSWER

Zn + Cu2+​​ → Zn2+​​ + Cu

4-6  ​​​​ Why is zinc described as being​​ 3xidized in this reaction?​​ 

[1 mark]

ANSWER​​ 

Zinc atoms loses (2) electrons s shown below

Zn → Zn2+​​ + 2e-

 

4-7  ​​​​ Zinc and copper can be used with another substance to​​ produce electricity.

Complete Figure 7 to show how zinc, copper and another substance can be used to light a lamp.

Label:

zinc

copper

the other substance used.

​​ 

[3 marks]

ANSWER

Zinc electrode and copper electrode both inserted into solution​​ (electrolyte) that would function as an electrochemical cell.