8462/1H June 2019

9 ​​ ​​​​ A​​ student​​ investigated​​ the​​ te mperature​​ change​​ in​​ the​​ reaction​​ between dilute sulfuric acid and potassium hydroxide solution.​​ 

1​​ This​​ is​​ the​​ method​​ used.

2​​ Measure​​ 25.0​​ cm3​​ potassium​​ hydroxide​​ solution​​ into​​ a​​ polystyrene​​ cup.

3​​ Record the temperature of the solution.

4​​ Add 2.0 cm3 dilute sulfuric acid.

5​​ Stir the​​ solution.

6​​ Record the temperature of the solution.

7​​ Repeat steps 3 to 5 until a total of 20.0 cm3 dilute sulfuric acid has been added.

 

9-1 ​​ ​​​​ Suggest why​​ the​​ student​​ used​​ a​​ polystyrene​​ cup​​ rather​​ than​​ a​​ glass​​ beaker​​ for​​ the​​ reaction. ​​ 

[2​​ marks]

ANSWER

Polystyrene is a better thermal insulator so reduces energy exchange with the surroundings.

Table 6 shows some of the​​ student’s results.

Volume​​ of​​ dilute​​ sulfuric​​ acid​​ added​​ in​​ cm3

Temperature​​ in​​ °C

0.0

18.9

2.0

21.7

4.0

23.6

6.0

25.0

8.0

26.1

10.0

27.1

Figure​​ 11​​ shows​​ some​​ of​​ the​​ data​​ from​​ the​​ investigation.

 

Figure​​ 11

9-2 ​​ Complete​​ Figure​​ 11:

  • plot​​ the​​ data​​ from​​ Table​​ 6

  • draw​​ a​​ line​​ of​​ best​​ fit​​ through​​ these​​ points

  • Extend​​ the​​ lines​​ of​​ best​​ fit​​ until​​ they​​ cross.​​   ​​ ​​ ​​ ​​​​ 

[4​​ marks]

 

ANSWER

 

 

9-3 ​​ ​​​​ Determine​​ the​​ volume​​ of​​ dilute​​ sulfuric​​ acid​​ needed​​ to​​ react​​ completely​​ with​​ 25.0​​ cm3​​ of​​ the​​ potassium​​ hydroxide​​ solution

 

ANSWER

Volume of dilute sulfuric acid to react completely = 11cm3

 

9-4​​ Determine​​ the​​ overall​​ temperature​​ change​​ when​​ the​​ reaction​​ is​​ complete.​​ 

Use​​ Figure​​ 11.​​          

[1​​ mark]

 

ANSWER

27.6 - 18.9 = 8.7oC