8462/1H June 2019

8 ​​ ​​ ​​​​ Copper forms two oxides, Cu2O and CuO A​​ teacher​​ investigated​​ an​​ oxide​​ of​​ copper.​​ 

Figure​​ 10​​ shows​​ the​​ apparatus

Figure​​ 10

This is the method used.

  • Weigh empty tube A.

  • Add some of the oxide of copper to tube A.

  • Weigh tube A and the oxide of copper.

  • Weigh tube B and drying agent.

  • Pass hydrogen through the apparatus and light the flame at the end.

  • Heat tube A for 2 minutes.

  • Reweigh tube A and contents.

  • Repeat steps 5 to 7 until the mass no longer changes.

  • Reweigh tube B and contents.

  • Repeat steps 1 to 9 with different masses of the oxide of copper.

 

8-1 ​​ ​​​​ Suggest​​ one​​ reason​​ why​​ step​​ 8​​ is​​ needed.

ANSWER

To make sure all of the oxide of copper​​ has​​ reacted and also​​ to make sure​​ that​​ all water (produced) is removed.

 

8-2 ​​ ​​​​ Explain​​ why​​ the​​ excess​​ hydrogen​​ must​​ be​​ burned​​ off. ​​ ​​​​ 

[2 marks]

ANSWER

As hydrogen is explosive so it needs to be prevented from​​ escaping into the air.

Figure​​ 10​​ is​​ repeated​​ here

Figure​​ 10

Table​​ 5​​ shows​​ the​​ teacher’s​​ results.

Table​​ 5

When an oxide of copper is heated in a stream of hydrogen, the word equation for the reaction is:

Copper​​ oxide​​ +​​ hydrogen​​ ​​ copper​​ +​​ water

 

8-3 ​​​​ Determine​​ the​​ mass​​ of​​ copper​​ and​​ the​​ mass​​ of​​ water​​ produced​​ in​​ this​​ experiment.​​ Use​​ Table​​ 5.

[2​​ marks]

ANSWER

Mass of CuO=115.47-105.72

Mass of CuO=​​ 9.75 g

Mass of Oxygen=115.47-114.38

mass of oxygen=​​ 1.09g

mass of Copper=mass of CuO-Mass of Oxygen

=9.75-1.09

=8.66g

Mass of water=123.38-120.93

mass of water=2.45 g

 

8-4 ​​ ​​​​ The​​ teacher​​ repeated​​ the​​ experiment​​ with​​ a​​ different​​ sample​​ of​​ the​​ oxide of copper.​​ The teacher found that the oxide of copper produced 2.54 g of copper and​​ 0.72 g of water.​​ 

Two possible equations for the reaction are:​​ 

Equation 1:Cu2O + H2 → 2 Cu + H2O​​ 

Equation 2:CuO + H2 → Cu + H2O​​ 

Determine which is the correct equation for the reaction in the teacher’s experiment.

Relative​​ atomic​​ masses​​ (Ar):H​​ =​​ 1O​​ =​​ 16Cu​​ =​​ 63.5

 

ANSWER

Step 1:​​ First calculate the moles of copper and water

Moles of Copper=2.5463.5

=0.04 mol

Moles of Water=0.7218

=0.04 mol

Step 2: Identify the smallest number of moles from the calculated mole

Both have the same moles, therefore we will take 0.04

Step 3: Divide calculate moles of Copper and water by 0.04 mol

For Copper,​​ =0.040.04

 

=1

For water=0.040.04

=1

 

Therefore, the ratio of Copper and water = 1:1

Hence, Equation 2 meets the requirement.