WCH11 June 2022

23.​​ Organic waste may be disposed of by landfill or incineration. Both processes produce gases.​​ 

(a) The main gases produced from a typical landfill are shown in the table.

(i) Name​​ the process that forms these gases in landfill.

​​ (1)

ANSWER

Decomposition

(ii) State the main environmental problem caused by landfill gases, identifying the gas or gases responsible.

​​ (2)

ANSWER

Global Warming due to methane and Carbon dioxide​​ emission.

(iii) One​​ tonne of landfill waste produces approximately 12.5dm3​​ of landfill gases per day.​​ 

Calculate the mass of carbon dioxide produced in a year by a typical landfill site which contains 90000 tonnes of waste.​​ 

Assume that the gas volume is measured at room temperature and pressure (r.t.p.). [Molar volume of gas at r.t.p. = 24.0dm3​​ mol1]​​ 

(3)

ANSWER

1 tonne produces 12.5 dm3 ​​ gases per day, therefore,​​ 

=12.5 x 365dm3 per day

9000 tones produces=  (9000 x 12.5 x 365)dm3

=4.10625x105 dm3 per day

Volume of CO22 = 45100× 4.10625×105 dm3 

                   =1.874 x 108 dm3 

 

 

 = 7.6 x 109 dm3 

Mass of CO2= n x Mr

  = 7.6 x 109 x 44

= 3.38 x 108

=338.77 tonnes

(b) Suggest two advantages of incineration over landfill.​​ 

(2)

ANSWER

i. less land is needed

ii. Can be used to generate electricity

(c) Environmental groups​​ prefer recycling to both landfill and incineration. Suggest one advantage of recycling.​​ 

(1)

ANSWER

Saves Energy / conserves resources.