8462/1H June 2021

5  ​​ ​​​​ This question is about salts

5-1  ​​​​ Name the salt produced by the neutralisation of hydrochloric acid with potassium​​ hydroxide. [1​​ mark]

ANSWER

Potassium chloride

5-2  ​​​​ Write an ionic equation for the neutralisation of hydrochloric acid with potassium​​ hydroxide.​​  [1​​ mark]

ANSWER

H+​​ + OH​​ → H2O

 

5-3  ​​​​ Soluble salts can be produced by reacting dilute hydrochloric acid with an insoluble solid.

Copper, copper carbonate and copper oxide are insoluble solids.

 

5-4 ​​ Which of these insoluble solids can be used to make a copper salt by reacting the solid with dilute hydrochloric acid?   ​​ ​​ ​​ ​​​​ [1 mark]

ANSWER

Copper carbonate and copper oxide only

 

A​​ student​​ makes​​ crystals​​ of​​ magnesium​​ sulfate.

This is the method used.

1.Add sulfuric acid to a beaker.

2.Warm the sulfuric acid.

3.Add a spatula of magnesium oxide to the beaker.

4.Stir the mixture.

5.Repeat steps 3 and 4 until there is magnesium oxide remaining in the beaker.

6.Filter the mixture.

7.Evaporate the filtrate gently until crystals start to form.

8.Leave the solution to finish crystallising.

 

5-5  ​​​​ Give​​ one​​ reason​​ for:

  • step​​ 2

  • step​​ 5

  • Step​​ 6.[3 marks]

 

ANSWER

 

  • Step 2: to speed up the reaction;

  • Step 5: to​​ make sure all the HCl acid reacts;

  • Step 6: to remove the excess magnesium oxide

5-6 ​​ How​​ should​​ the​​ filtrate​​ be​​ evaporated​​ gently​​ in​​ step​​ 7?​​   ​​ ​​ ​​ ​​ ​​ ​​​​ [1 mark]

ANSWER

Using a boiling water bath or using an electric heater.

5-6  ​​​​ Iron chloride is produced by​​ heating iron in chlorine gas. The equation for​​ the reaction is:

2​​ Fe​​ +​​ 3​​ Cl2​​ ​​ 2​​ FeCl3

Calculate​​ the​​ volume​​ of​​ chlorine​​ needed​​ to​​ react​​ with​​ 14​​ g​​ of​​ iron. You should calculate:

  • the​​ number​​ of​​ moles​​ of​​ iron​​ used

  • the​​ number​​ of​​ moles​​ of​​ chlorine​​ that​​ react​​ with​​ 14​​ g​​ of​​ iron

  • the​​ volume​​ of​​ chlorine​​ needed.

Relative atomic mass (Ar): Fe = 56​​ 

The​​ volume​​ of​​ 1​​ mole​​ of​​ gas​​ =​​ 24​​ dm3[3 marks]

 

ANSWER

MolesofIron=1456

 

molesofiron=0.25mol

Now by seeing the equation, the molar ratio of Fe:Cl2 =​​ 2:3

Therefore one mole of iron reacts with​​ 32​​ of Cl2

Therefore, 0.25 mol. of Fe will react with​​ 32×0.25mol​​ of Cl2​​ 

=0.375molofCl2

 

=0.375mol×24dm3

=9dm3