8462/1H June 2018

This question is about metals and metal compounds

Iron pyrites is an ionic compound. Figure 1 shows a structure for iron pyrites.

Figure 1

Determine the formula of iron pyrites. Use​​ Figure 1.    ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​ ​​​​ 

[1​​ mark]

ANSWER

FeS2

An​​ atom​​ of iron​​ is​​ represented​​ as​​ Fe2656.

Give the number of protons, neutrons and electrons in​​ this atom of iron.            

[3 marks]

Number​​ of​​ protons:  ​​​​ ______________

Number​​ of neutrons: ______________

Number​​ of electron: ​​ ______________

ANSWER

Number​​ of​​ protons:  ​​​​ 26

Number​​ of neutrons:​​ 30

Number​​ of electron: ​​ 26

Iron is a transition metal. Sodium is a Group 1 metal.​​ 

Give​​ two​​ differences​​ between​​ the​​ properties​​ of​​ iron​​ and​​ sodium.

[2​​ marks]

ANSWER

Student may select any two (as required):

  • iron has a higher melting / boiling point as compared to Group 1 metal Sodium metal

  • iron is denser than Group 1 metal Sodium metal

  • iron is harder than Group 1 metal​​ Sodium metal

  • iron is stronger than Group 1 metal Sodium metal

  • iron is less reactive than Group 1 metal Sodium metal

  • iron has ions with different charges while Group 1 metal Sodium metal has only single charge i.e. +1

  • iron forms coloured compounds while Group 1 metal Sodium metal form white solids

  • iron can be a catalyst while Group 1 metal Sodium metal cannot

Nickel​​ is​​ extracted​​ from​​ nickel​​ oxide​​ by​​ reduction​​ with​​ carbon.​​ 

Explain​​ why​​ carbon​​ can​​ be​​ used​​ to​​ extract​​ nickel​​ from​​ nickel​​ oxide.​​ 

[2​​ marks]

ANSWER

Carbon is more reactive than nickel so carbon will displace or replace nickel from nickel oxide or in other words carbon will remove oxygen from nickel oxide.

An equation for the reaction is: NiO + C​​ ​​ Ni + CO

Calculate the​​ percentage atom economy for the reaction to produce nickel.​​ 

Relative atomic masses (Ar): C = 12, Ni = 59; Relative formula mass (Mr): ​​ NiO = 75. Give your answer to 3 significant figures.​​  

[3 marks]

ANSWER

Total Mass of Reactant=75 + 12 

=87

Percentage atom economy=5987×100

=67.8 %